2024.11.27 09:50 hashamean A small abandoned house on the shore of the Indian Ocean
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2024.11.27 09:50 Gothic143_69 F19 Bored as hell looking for someone to chat
I don't know what else to say about myself other than that my name is Laura, everyone calls me Aura, and I like to yap. That's pretty much what the title says.
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2024.11.27 09:50 patroln Copper vs Lead core
So long story short, I have a couple of 308s that I'm using to practice and hopefully bag me a deer or 2 on a regular basis.
Only problem is near enough everytime I'm at the range or gunshop etc I keep hearing how 308W isn't enough for Sambar and I should really get a 30-06 minimum, no I'm not expecting it to shoot deer at 400+ meters nor am I expecting to a big sambar stag to walk out wearing level 4 plates.
But one of my 308W really likes the hornady American whiteail (interlock) 150Gr at under an inch all day.
But also shoots winchester copper impact 150gr at 1-1.1" semi consistently.
I've also had OK 1.5-2" groups of Remington PSP 180GR now due to some peer pressure I zeroed the rifle for the 180's as "thats minimum for sambar mate" however I do not like the lack of consistency that I get with them when I know I have ammo that will shoot far better in the safe. So I'm considering re- zeroing the rifle for the copper impacts, so my question is what would you do? Stick to the 180s or go to something like a monolithic projectile?
submitted by patroln to Ausguns [link] [comments]
2024.11.27 09:50 Rude-Air3854 Woman, below I have provided north and south D7-D9 charts. What will my spouse be/ look like? Where or when could I meet them?
submitted by Rude-Air3854 to vedicastrology [link] [comments]
2024.11.27 09:50 addnaan How is my new tank ?
This is my second tank, i am very proud of this one, tried to give a red and dark theme to it. Will be adding some fish with some interesting colours for example galaxy rasbora. Right now I have 4 albino cory(will be adding more ), 5 hillstream loache and 15-20 shrimps. I would also really appreciate if you can suggest me a name for it …. I was thinking of “ruby haven” submitted by addnaan to PlantedTank [link] [comments] |
2024.11.27 09:50 Dangerous-State1743 I think I found the crux of my issue, can someone help me? TFM
So I have read the freedom model and I believe I understand it. It makes a lot of sense to me, but I still find myself wanting to use pmo. I realize that my "addiction" was never to pmo but to fantasies that I attach value to via beliefs, and p just helps the fantasy. So I want to challenge these beliefs.
This process is what happens 95% of the time I use: In the moment I am always in bed, and I start thinking about sexual scenarios because I really don't like being just aware and bored while trying to sleep. I go from slightly sexual scenarios to very sexual scenarios and then I start thinking about having a pmo session to quell my self induced cravings. That's when I try to do things like tell myself that I have created a fake overblown value of this fantasy or other things. But eventually I either just continue fantasizing, or just pmo.
The thing is, I know I don't need it, but it's clear that I want it. I admit I enjoy this whole process, but it's costly to me. I want to make the fantasy less valuable. How do I do that in this situation? Should I combat my specific interests? Should I debunk it really giving me what I'm looking for?
What I believe are the Main Fantasizing benefits to me: -Helps me avoid thinking about life and isn't disruptive to me trying to sleep -It's pleasurable -Sense of control -Boredom relieving
Any ideas on addressing these? thanks.
submitted by Dangerous-State1743 to pmohackbook [link] [comments]
2024.11.27 09:50 unknownforever133 My car won’t go into gear
Car won’t go into reverse or drive I can’t feel the transmission engage whenever I try to shift the car. Thought the cable was broken but the cable still moves if I try to put the car in gear what could this be
submitted by unknownforever133 to MechanicAdvice [link] [comments]
2024.11.27 09:50 Charedi MSCS vs MIS
Profile- 8.04 GPA VIT Vellore, 315 GRE (168 quant), 3.5 yoe as backend developer at Motorola Solutions. 8.5 IELTS. No research Since my profile is just average, im doubting my chances at MSCS at a really good school(Upenn, Umass amherst,Stony brook etc), should i apply for MIS just to have a better chance of going to a better college? Or maybe even MSCE?My main goal is to get a job as a developer and if i can get a product management role due to MIS then i’m okay with that as well.Do companies prefer mscs grads for developer roles or is it just about who can clear the leetcode round?? Any advice would be greatly appreciated!
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2024.11.27 09:50 Advanced_Drink_8536 Homan says he is willing to put Denver mayor ‘in jail’ over deportation position
submitted by Advanced_Drink_8536 to AnythingGoesNews [link] [comments] |
2024.11.27 09:50 marsicano I created a tiktok-like website ideal for promoting your OnlyFans
To grow your Onlyfans profile create a profile and upload a short video preview of your content to https://tikfap.me . Don't forget to include the link to OF in the description of the videos you upload! For best results set a profile picture and periodically add a small video! 🚀
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2024.11.27 09:50 Steinchen IAE 2954 Academy Missions-Tutorial
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2024.11.27 09:50 Ahoy-Alternative Yesterday Once More by Carpenters . Piano . Lyrics
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2024.11.27 09:50 sad39 Nový Fiala: Některé moje postupy teď překvapují i můj tým
submitted by sad39 to czech [link] [comments] |
2024.11.27 09:50 bzpc Adonde mudaron a los senegaleses de Once?
Eso, para comprar un par de cosas berretas sin irme a Flores
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2024.11.27 09:50 djkkath LOTR FANS, will you be watching War of the Rohirrim in cinema? If so, IMAX or just 2D?
I was born in the early 2000's and this is going to be my first time watching anything LOTR in the cinema and I am VERY excited. Though I want to experience it in IMAX, I'm not so sure if it's worth it. So, I am kind of leaning towards the regular 2d cinema. Thoughts? submitted by djkkath to FilmClubPH [link] [comments] |
2024.11.27 09:50 Business-Purchase934 What's the most breathtaking moment you've ever experienced?
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2024.11.27 09:50 CherryBlossomEnding tripleS and Ai Tomioka added to the lineup of 2024 Seoul Con x WORLD K-POP FESTIVAL
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2024.11.27 09:50 Totallyrealyamumreal 5uc on Siemens dishwasher
Woke up today, went to the kitchen and saw that '5uc' was on the dishwasher screen. Any ideas?
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2024.11.27 09:50 rqrdi fake right? the print font and the embro are sus
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2024.11.27 09:50 awokenexperiment Deltarune party singles :>
Bonded with my coworker over us both being into dr but forgot to ask him which his party name of choice is...gotta be prepared for our next shift together 8) submitted by awokenexperiment to kandi [link] [comments] |
2024.11.27 09:50 1629uknow typa shit Peggy would get tattooed
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2024.11.27 09:50 Aristannnnnn Homemade pasta
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2024.11.27 09:50 Crazy_Bar_7176 the shitfuck
submitted by Crazy_Bar_7176 to SuperMechs [link] [comments]
2024.11.27 09:50 According-Gain-4408 Mass Spec Peak Problem
Background info:
I synthesised a molecule from reagents of masses 223 and 252. It was catalysed by DMAP (mass= 122).
I've been trying to isolate my product of mass 457 (esterification) via column chromatography for a month now, without much success (cannot separate non-esterified reagent). Yesterday, I used the Prep-HPLC and gave my molecules peak to the LCMS. I saw 3 peaks:
Polar peak with major mass of 122 (4% Rel. INT)
Polar peak of 115 (no idea what this is)
And the peak of my material, with 2 major M/Z values: 480 (M+Na, parent peak), and 579 (30% Rel. Int.)
I noticed how 579 = 457 + 122.
My Question Now Is:
Even after HPLC, could DMAP not have been separated, is it possible that DMAP somehow binds to my molecule? Obvious answer would be yes, but then I would expect a mass lower than the sum of my molecule + DMAP, as some atom should leave to for DMAP to bond. My molecule contains an ester, carboxylic acid and thioacetal groups.
submitted by According-Gain-4408 to OrganicChemistry [link] [comments]
2024.11.27 09:50 Papershellhigh Do you guys print your own backdrops?
I’ve been working as a commercial photographer for a year now and am looking to expand my collection of props and backdrops. I’m based in Asia and have noticed that most of the backdrops I like are from Western countries. While I don’t mind the cost of the props, dealing with customs has been such a hassle that I’m wondering if I can print my own backdrops locally. There are a few large-scale printing shops near me that offer gloss and matte options with different GSMs. I’m curious about what I should look for when printing backdrops myself. For example, what kind of paper or material would work best? I know Etsy offers downloadable files and for simple geometric patterns, I could even design something in Photoshop. The backdrop I want to replicate is a vinyl print - would that be a good option to aim for? I’ve also browsed Amazon but didn’t find the designs I wanted. I did come across translucent PVC backdrops - did not like them. Any advice would be greatly appreciated! submitted by Papershellhigh to AskPhotography [link] [comments] |